has one structural isomer
Methane

methane
Methane
has one structural isomer
Ethane

ethane
Ethane
has one structural isomer
Propane

propane
Propane
has two structural isomers
Butane

butane
Butane

2-methylpropane
Butane
has three structural isomers
Pentane

pentane
Pentane
2-methylbutane
Pentane

2,2-dimethylpropane
Pentane
has five structural isomers
Hexane

hexane
Hexane

2-methylpentane
Hexane

3-methylpentane
Hexane

2,2-dimethylbutane
Hexane

2,3-dimethylbutane
Hexane
has nine structural isomers
Heptane

heptane
Heptane
2-methylhexane
Heptane

3-methylhexane
Heptane

2,2-dimethylpentane
Heptane

2,3-dimethylpentane
Heptane

2,4-dimethylpentane
Heptane
3,3-dimethylpentane
Heptane

3-ethylpentane
Heptane

2,2,3-trimethylbutane
Heptane
has eighteen structural isomers
Octane
has thirty-five structural isomers
Nonane
has seventy-five structural isomers
Decane